Quantum Mechanics/Symmetry and Quantum Mechanics

The idea of symmetry plays a huge role in physics. We have already used symmetry arguments in the theory of relativity -- applying the principle of relativity to obtain the dispersion relation for relativistic matter waves is just such an argument. In this section we begin to explore how symmetry can be used to increase our understanding of quantum mechanics.

Free Particle

The wave function for a free particle of definite momentum, P, and energy, E is given by

$\psi =\exp i(kx-\omega t)=\exp i{\frac {Px-Et}{\hbar }}$

For this wave function |ψ|²=1 everywhere, so the probability of finding the particle anywhere in space and time is uniform - just like the particle energy.

This contrasts with the probability distribution which arises if we assume a free particle to have the wave function

$\psi =\sin {\frac {Px-Et}{\hbar }}\quad |\psi |^{2}=\sin ^{2}{\frac {Px-Et}{\hbar }}$

In this case the probability varies with position and time, which is inconsistent with a uniform probability distribution. This solution is less symmetric than the problem.

Symmetry and Definiteness

Quantum mechanics is a probabilistic theory, in the sense that the predictions it makes tell us, for instance, the probability of finding a particle somewhere in space. If we know nothing about a particle's previous history, and if there are no physical constraints that would make it more likely for a particle to be at one point along the axis than any another, then the probability distribution must be P(x)=constant.

This is an example of a symmetry argument. Expressed more formally, it states that if the above conditions apply, then the probability distribution ought to be subject to the condition P(x+d)=P(x) for any constant value of d . This can only be true if P(x) is a constant.

In the language of physics, if there is nothing that gives the particle a higher probability of being at one point rather than another, then the probability is independent of position and the system is invariant under displacement in the direction.

The above argument doesn't suffice for quantum mechanics, since as we have learned, the fundamental quantity describing a particle is not the probability distribution, but the wave function . Thus, the wave function rather than the probability distribution ought to be the quantity which is invariant under displacement.

This condition turns out to be too restrictive, because it implies that ψ is constant but we know that a one-dimensional plane wave, which describes a particle with a uniform probability of being found anywhere along the axis, has the form

$\psi =\exp ikx\,$

(For simplicity we temporarily ignore the time dependence.) If we make the substitution x→x+d in a plane wave, we get

$\psi =\exp ik(x+d)=\exp ikd\exp ikx\,$

The wave function is thus technically not invariant under displacement, in that the displaced wave function is multiplied by the factor exp(ikd). However, the probability distribution of the displaced wave function still equals one everywhere, so there is no change in what we observe.

Thus, in determining invariance under displacement, we are allowed to ignore changes in the wave function which consist only of multiplying it by a complex constant with an absolute value of one; i.e one of the form exp(iα) with α real. Such a multiplicative constant is called a phase factor, and α the phase.

It is easy to convince oneself by trial and error or by more sophisticated means that the only form of wave function which satisfies this condition is

$\psi =A\exp ikx\,$

where A is a (possibly complex) constant. This is just in the form of a complex exponential plane wave with wavenumber k. Thus, not only is the complex exponential wave function invariant under displacements in the manner defined above, it is the only wave function which is invariant to displacements. Furthermore, the phase factor which appears for a displacement d of such a plane wave takes the form exp(ikd), where k is the wavenumber of the plane wave.

As an example, let us see if a wave packet is invariant under displacement. Let's define a wave packet consisting of two plane waves:

$\psi =e^{ik_{1}x}+e^{ik_{2}x}$

Making the substitution x→x+d in this case results in

${\begin{matrix}\psi &=&e^{ik_{1}(x+d)}+e^{ik_{2}(x+d)}\\&=&e^{ik_{1}d}e^{ik_{1}x}+e^{ik_{2}d}e^{ik_{2}x}\\&\neq &\left[e^{ik_{1}(x+d)}+e^{ik_{2}(x+d)}\right]e^{i\alpha }\end{matrix}}$

no matter what value α has.

The impossibility of writing the displaced wavefunction as the original multiplied by a phase factor lends plausibility to the assertion that a single complex exponential is the only possible form of the wave function that is invariant under displacement.

Notice that the wave packet does not have definite wavenumber, and hence, momentum. In particular, non-zero amplitudes exist for the associated particle to have either momentum $\hbar k_{1}$ or $\hbar k_{2}$ . This makes sense from the point of view of the uncertainty principle -- for a single plane wave the uncertainty in position is complete and the uncertainty in momentum is zero. For a wave packet the uncertainty in position is reduced and the uncertainty in the momentum is non-zero.

However, we see that this idea can be carried further: A definite value of momentum must be associated with a completely indefinite probability distribution in position. This corresponds to a wave function which has the form of a complex exponential plane wave.

However, such a plane wave is invariant under a displacement d, except for the multiplicative phase factor , which has no physical consequences since it disappears when the probability distribution is obtained. Thus, we see that invariance under displacement of the wave function and a definite value of the momentum are linked, in that each implies the other:

Invariance under displacement ⇔ Definite momentum

We can compare this with classical mechanics, where we saw that if the energy is invariant under displacement then momentum is conserved, and similarly for generalised coordinates.

The above equivalence can also be extended to arbitary coordinates.

In particular, since the time dependence of a complex exponential plane wave is

$e^{-i\omega t}=e^{-i{\frac {Et}{\hbar }}}$

we have by analogy with the above argument that

Invariance under time shift ⇔ Definite energy

Thus, invariance of the wave function under a displacement in time implies a definite value of the energy of the associated particle.

Another useful instance of this is

Invariance under rotation ⇔ Definite angular momentum

since the same connection between rotation and angular momentum holds as in classical mechanics.

In the previous chapter we assumed that the frequency (and hence the energy) was definite and constant for a particle passing through a region of variable potential energy. We now see that this assumption is justified only if the potential energy doesn't change with time. This is because a time-varying potential energy eliminates the possibility of invariance under time shift.

Compatible Variables

We already know that definite values of certain pairs of variables cannot be obtained simultaneously in quantum mechanics. For instance, the indefiniteness of position and momentum are related by the uncertainty principle -- a definite value of position implies an indefinite value of the momentum and vice versa. If definite values of two variables can be simultaneously obtained, then we call these variables compatible. If not, the variables are incompatible.

If the wave function of a particle is invariant under the transformations associated with both variables, then the variables are compatible. For instance, the complex exponential plane wave associated with a free particle is invariant under displacements in both space and time. Since momentum is associated with space displacements and energy with time displacements, the momentum and energy are compatible variables for a free particle.

Compatibility and Conservation

Variables which are compatible with the energy have a special status. The wave function which corresponds to a definite value of such a variable is invariant to displacements in time. Thus, if the wave function is also invariant to some other transformation at a particular time, it is invariant to that transformation for all time. The variable associated with that transformation thus retains its definite value for all time -- i. e., it is conserved.

For example, the complex exponential plane wave implies a definite value of energy, and is thus invariant under time displacements. At time t'=0, it is also invariant under displacements, which corresponds to the fact that it represents a particle with a known value of momentum. However, since momentum and energy are compatible for a free particle, the wave function will represent the same value of momentum at all other times.

In other words, if the momentum is definite at t=0, it will be definite at all later times, and furthermore will have the same value. This is how the conservation of momentum (and by extension, the conservation of any other variable compatible with energy) is expressed in quantum mechanics.

We will see later how to describe this in terms of operators.