9-1 Chemistry/Identification of ions

Flame tests can be used to identify some cations (positive ions).

Flame tests

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Compound colour of flame Photo
Lithium Crimson flame
 
Sodium Yellow flame
 
Potassium Lilac flame
 
Calcium Orange-red flame
 
Copper Green flame
 

If a sample containing a mixture of ions is used, some flame colours can be masked.

Metal hydroxides

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Sodium hydroxide solution can be used to identify some cations:

  • Aluminium
  • Calcium
  • Magnesium

Ions form white precipitates when sodium hydroxide solution is added but only the aluminium hydroxide precipitate dissolves in excess sodium hydroxide solution.