Quantum Chemistry/Example 1

Write a question and its solution that quantitatively demonstrates the Heisenberg uncertainty principle for a quantum harmonic oscillator in the ground state (n=0).

Find ⟨x⟩, ⟨x2⟩, ⟨px⟩ and ⟨px2⟩ for a quantum harmonic oscillator in the ground state, then determine the uncertainty on the position and momentum. Is the product of the uncertainty on position and momentum consistent with the Heisenberg's Uncertainty Principle?Edit

Heisenberg's Uncertainty Principle

 

The wavefunction of a quantum harmonic oscillator in the ground state is:

  Using this wavefunction the average position and the average of the square of the position can be calculated.


The average position:

 

 

 

 

use  

 

 

 



The average square of the position:

 

 

 

 

use  

 

 

use   and  

 

 

 



The uncertainty on the position:

 

 

 


The average momentum:

 

 

 

 

 

 

use  

 

 

 


The average square of the momentum:

 

 

 

 

 

 

use  

 

use  

 

 

use   and  

 

 

 

 



The uncertainty on the momentum:

 

 

 


The product of the uncertainty on the position and the uncertainty on the momentum is:

 

 


This is equal to  , therefore, a quantum harmonic oscillator in the ground state is consistent with the Heisenberg Uncertainty Principle.