Introduction to Mathematical Physics/Quantum mechanics/Linear response in quantum mechanics

Let be the average of operator (observable) . This average is accessible to the experimentator (see (references)). The case where is proportional to is treated in (references) Case where is proportional to is treated here. Consider following problem:

Problem:

Find such that:

with

and evaluate:

Remark: Linear response can be described in the classical frame where Schr\"odinger equation is replaced by a classical mechanics evolution equation. Such models exist to describe for instance electric or magnetic susceptibility.

Using the interaction representation\footnote{ This change of representation is equivalent to a WKB method. Indeed, becomes a slowly varying function of since temporal dependence is absorbed by operator }

and

Quantity to be evaluated is:

At zeroth order:

Thus:

Now, has been prepared in the state , so:

At first order:

thus, using properties of Dirac distribution:

Let us now calculate the average: Up to first order,

Indeed, is zero because is an odd operator.

where, closure relation has been used. Using perturbation results given by equation ---pert1--- and equation ---pert2---:

We have thus:

Using Fourier transform\footnote{ Fourier transform of:

and Fourier transform of:

are different: Fourier transform of does not exist! (see (references)) }