Advanced Inorganic Chemistry/Matrix (1.3)

A matrix is a rectangular array of quantities or expressions in rows (m) and columns (n) that is treated as a single entity and manipulated according to particular rules.[1] The dimension of a matrix is denoted by m × n. In inorganic chemistry, molecular symmetry can be modeled by mathematics by using group theory. The internal coordinate system of a molecule may be used to generate a set of matrices, known as a representation, that corresponds to particular symmetry operations.[2] Matrix modeling thus allows for symmetry operations performed on the molecule to be represented in an identical fashion mathematically.

Matrix Operations Edit

Addition Edit

The sum of two matrices, A and B, is carried out by adding or subtracting the element of one matrix with the corresponding element of another matrix. These operations may only be performed on matrices of identical dimension.

A + B =   where i refers to a particular row and j to a particular column.



Scalar Multiplication Edit

Multiplication of a matrix by a scalar, c, multiplies every element within the matrix by the scalar.

cA = c · Ai,j



Matrix Multiplication Edit

Matrix multiplication entails computing the dot product of the row of one matrix, A, with the column of another matrix, B. Matrix multiplication is only defined if the number if columns of A, denoted by n, is equal to the number of rows of B, denoted by m. Their product is then the m × n matrix, C. Matrix multiplication entails some mathematical properties. First, it is associative; in other words, (A × B) × C = A × (B × C). Furthermore, matrix multiplication is not commutative; in other words, A × B =/= B × A

Cm×n = Am×c · Bc×n =  



Row Operations Edit

There are three kinds of elementary row operations that are used to transform a matrix:

Type Definition Operation
Row Switching The swapping of one row with that of another row  
Row Addition The addition of a multiple of one row to another row  
Row Multiplication Multiplication of a row by a scalar, c, with c ≠ 0 c 

Square Matrices Edit

Square matrices are matrices where the number of rows and number of columns are equal, resulting in an n × n matrix.

Identity Matrix Edit

The identity matrix, In, is a diagonal matrix which has all elements along the main diagonal equal to 1 and all other elements equal to 0. Multiplication of another matrix by the identity matrix leaves the first unchanged. Moreover, multiplication with the identity matrix is commutative; in other words, A × I = I × A.


A·I3 =  

Trace Edit

Only applicable to square matrices, the trace or character,  , of a matrix is the sum of its diagonal entries along the main diagonal.

Determinant Edit

The determinant of a matrix, denoted det(A), is a real number computed from a square matrix. A non-zero determinant implies matrix invertibility, which further implies that the set of linear equations comprising the matrix has exactly one solution.

For a 2 × 2 matrix, the determinant is computed as follows:

det(A) =  

For a 3 × 3 matrix, the determinant is computed as follows:

det(A) =  

Higher order determinants may be calculated by using Cramer's Rule.

References Edit

  1. "Matrix [Def. 3]. In Oxford Dictionaries (American English) (US)". Retrieved 2016-05-31.
  2. Pfenning, Brian W. (2015). Principles of Inorganic Chemistry. Hoboken: John Wiley & Sons, Inc. p. 195. ISBN 9781118859100.