Statistical Mechanics/Boltzmann and Gibbs factors and Partition functions/Boltzmann Factors
The first 'method of simplification' involves considering a thermal reservoir, basically a temperature bath that will keep our system of consideration at a constant temperature T.
Then by the fundamental assumption, given two energy states:
Now, because of the Taylor Series, and in the presence of an infinitely large reservoir the higher-order terms vanish:
Using this simplification we can write the previous exponential form of the ratio of probabilities:
where is known as a Boltzmann factor. We will expand on its usefulness in the next section.Last modified on 23 July 2009, at 20:09